Effect on Different Amount of TiO2 P25 powder for Dye-Sensitized Solar Cell application
Keywords:
Dye-Sensitized Solar Cell, TiO2, Thickness, Efficiency,Abstract
Titanium Dioxide (TiO2) has been successfully prepared using the spray pyrolysis method. Then it was optimized by conducting several repetition procedures and deposited on fluorine tin oxide (FTO) substrate. The amount of TiO2 P25 was varied from 0.1 grams (g) to 0.5 g in order to study the exact amount of TiO2 P25 needed to produce the highest efficiency solar cell result. All the thin films were annealed at fixed temperature at 500oC within 3 hours. The thickness of the thin film was measured through a surface profiler. From the measurement, it can be concluded that the utilization of different amount of TiO2 P25 affects the thickness of thin film. The properties of TiO 2 thin film were investigated by Field Emission Scanning Electron Microscopy (FE-SEM), X-ray Diffraction (XRD) and Four Point Probes. The amount of TiO2 P25 shows the notable effect on morphological and structural of deposit-TiO2. The optimum porosity of thin film was observed when 0.3g of TiO2 P25 has been used while XRD patterns exhibit anatase and rutile structures based on the peak existed. The adsorption of dye molecules increased when the thickness of thin film increased due to the increase in crystal size. Hence, it improves the short circuit density respectively. The efficiency of Dye-Sensitized Solar Cell increased as short circuit density and film thickness increased. Based on this research, the amount of 0.3g TiO2 P25 with thickness 17.89 µm can be used in DyeSensitized Solar Cell applications with the optimum power conversion efficiency measured by solar simulator which is 1.84%.References
Kumari, N. Sanjeevadharshini, M. Dissanayake, G. Senadeera and C. Thotawatthage, "The effect of TiO2 photo anode film thickness on photovoltaic properties of dye-sensitized solar cells", Ceylon Journal of Science, vol. 45, no. 1, p. 33, 2016.
A. Mathew, G. Rao and N. Munichandraiah, "Effect of TiO2 electrode thickness on photovoltaic properties of dye sensitized solar cell based on randomly oriented Titania nanotubes", Materials Chemistry and Physics, vol. 127, no. 1-2, pp. 95-101, 2011.
M. Sahal, B. Hartiti, A. Ridah, M. Mollar and B. Marí, "Structural, electrical and optical properties of ZnO thin films deposited by sol–gel method", Microelectronics Journal, vol. 39, no. 12, pp. 1425-1428, 2008.
Yu, H. Yu, B. Cheng, M. Zhou and X. Zhao, "Enhanced photocatalytic activity of TiO2 powder (P25) by hydrothermal treatment", Journal of Molecular Catalysis A: Chemical, vol. 253, no. 1-2, pp. 112-118, 2006.
A. Nakaruk and C. Sorrell, “Conceptual model for spray pyrolysis mechanism: fabrication and annealing of titania thin films,” Journal of Coatings Technology and Research, vol. 7, no. 5, pp. 665–676, 2010.
P. Gemeiner and M. Mikula, "Efficiency of dye-sensitized solar cells with various compositions of TiO2 based screen printed photoactive electrodes", Acta Chimica Slovaca, vol. 6, no. 1, 201
Downloads
Published
How to Cite
Issue
Section
License
TRANSFER OF COPYRIGHT AGREEMENT
The manuscript is herewith submitted for publication in the Journal of Telecommunication, Electronic and Computer Engineering (JTEC). It has not been published before, and it is not under consideration for publication in any other journals. It contains no material that is scandalous, obscene, libelous or otherwise contrary to law. When the manuscript is accepted for publication, I, as the author, hereby agree to transfer to JTEC, all rights including those pertaining to electronic forms and transmissions, under existing copyright laws, except for the following, which the author(s) specifically retain(s):
- All proprietary right other than copyright, such as patent rights
- The right to make further copies of all or part of the published article for my use in classroom teaching
- The right to reuse all or part of this manuscript in a compilation of my own works or in a textbook of which I am the author; and
- The right to make copies of the published work for internal distribution within the institution that employs me
I agree that copies made under these circumstances will continue to carry the copyright notice that appears in the original published work. I agree to inform my co-authors, if any, of the above terms. I certify that I have obtained written permission for the use of text, tables, and/or illustrations from any copyrighted source(s), and I agree to supply such written permission(s) to JTEC upon request.